词汇 | enthalpy |
释义 | BETA Examples of enthalpyenthalpy isn’t in the Cambridge Dictionary yet. You can help! Thus, the enthalpy change for strand association is markedly temperature-sensitive. We notice that enthalpy can be a multi-valued function of temperature because a phase change is allowed. The variation in the enthalpy transfer parameter was obtained by varying the free-stream moisture content. One has to consider the pressure effects appearing in the conservation equation of enthalpy. The flow of a gas whose sound speed and enthalpy are independent variables will now be considered. In this derivation the parameters were adjusted to produce accurate room-temperature enthalpies of vaporization and vapor pressures or densities of a set of solvated alkanes. Enthalpy-driven stabilization leads to greater resilience while entropy-driven stabilization leads to lower resilience. Overall, the interactions are characterised by enthalpy-entropy compensation mechanisms, as typically found for other groove-binding ligands. This loss might be compensated by favourable interaction energy contributing to binding enthalpy. Application of a generalized enthalpy-entropy relationship to binding cooperativity and weak associations in solution. Dissecting the free energy of binding into enthalpy and entropy is, we believe, crucial to addressing the problem of rational ligand design. Equations (2.3), (2.4), (2.7) and (2.8) employ the extension to the enthalpy method. For a gas whose enthalpy and sound speed are functionally related, the results are a generalization of those for a perfect gas. Thus, weak stacking interactions (low enthalpy) in the duplex state are associated with a wider range of available conformational states (small entropy change). It is generally observed that the enthalpy difference is large and favourable, and that base stacking dominates this term. The plasma is accelerated by the thermal mechanism in which the enthalpy of the particles is transformed into kinetic energy. It is possible that the low enthalpy, weakly bound states trapped with cryo-cooling are exactly the room-temperature transient states that need to be observed. |
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