Examples of isomerization

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Photosensitivity depends on the product of molar absorbance and quantum efficiency of isomerization (g).
The second criterion points towards a sugar molecule, rather than an amino acid, because the keto-enol kinetics is much faster than the substitution isomerization kinetics for amino acids.
Domain catalyzed chemical reactions : a molecular dynamics simulation of isomerization kinetics.
The system was bistable at high concentrations due to the isomerization kinetics and the kinetics resulted in a dominance of one of the species at late times.
Glyceraldehyde fulfils the physico-chemical and biochemical conditions for having performed such a symmetry break by self-assembling with active isomerization kinetics.
This is then followed by isomerization and hydrogenation.
Kinetics of mutual isomerization of trioses and their dehydration to methylglyoxal.
Mechanism of isomerization of rhodopsin studied by use of 11-cis-locked rhodopsin analogues excited with a picosecond laser.
They proposed that interactions with the protein cavity in rhodopsin could alter the energy surface in ways that speed up the isomerization.
Calculated free-energy profile of the isomerization of dihydroxyacetone phosphate to glyceraldehyde-3-phosphate in water (a) and as catalyzed by triosephosphate isomerase (b).
In principle, thiourea could also be formed, as a result of the isomerization of thiocyanate : !
It is here that the isomerization kinetics play a crucial role.
Since the isomerization barrier lies well below the total available energy, the cis and trans forms are expected to be present in equal amounts.
Real-time detection of 60-fs isomerization in a rhodopsin analog containing eight-membered-ring retinal.
A possible mechanism involving a previous enamine-imine tautomerism must be discarded because it implies a much larger barrier than the direct isomerization process.
The isomerization kinetics are active in the fluid state and in an aqueous solution especially at high temperatures.
It is not active in crystals, but is active in the fluid state and at high temperature, especially in the keto-enol isomerization kinetics for sugar.
Moreover, it would adjust the threshold in response to any noise source, whether it is background light, thermal isomerizations, or continuous dark noise.

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